{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II)

被引:4
作者
Kargar, Hadi [1 ]
Kia, Reza [2 ,3 ]
Abbasian, Saeideh [1 ]
Tahir, Muhammad Nawaz [4 ]
机构
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
[2] Islamic Azad Univ, Plasma Phys Res Ctr, Xray Crystallog Lab, Sci & Res Branch, Tehran, Iran
[3] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran
[4] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词
MONOHYDRATE;
D O I
10.1107/S1600536812002085
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni(C19H16Cl4N2O2)], the Ni-II ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 24.8 (2)degrees. In the crystal, molecules are linked into chains along the b axis by weak C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions. An intermolecular Cl center dot center dot center dot Cl [3.4564 (19) angstrom] interaction is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 angstrom).
引用
收藏
页码:M193 / U1020
页数:12
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