Spin-glass transition in single-crystal BiFeO3

被引:276
作者
Singh, Manoj K. [1 ]
Prellier, W. [2 ]
Singh, M. P. [2 ]
Katiyar, Ram S. [1 ]
Scott, J. F. [3 ]
机构
[1] Univ Puerto Rico, Dept Phys, Rio Piedras, PR 00931 USA
[2] ENSICAEN, CNRS, Lab CRISMAT, UMR 6508, F-14050 Caen, France
[3] Univ Cambridge, Dept Earth Sci, Cambridge CB2 3EQ, England
关键词
D O I
10.1103/PhysRevB.77.144403
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic properties of BiFeO3 (BFO) single crystals with rhombohedral symmetry (R3c) were measured in the temperature range of 4.2-350 K. Zero field cooled (ZFC) and field cooled magnetization curves split below 250 K with a sharp cusp around 50 K in the ZFC curves revealing spin-glass behavior in BFO single crystals. The observed coercive field increases with decreasing temperature, suggesting week ferromagnetism below similar to 10 K and spin glass behavior below similar to 120 K. The cusps around the freezing temperature [T-f(omega)] which are frequency dependent confirm the spin-glass behavior in BFO single crystals with spin freezing temperature (T-SG=29.4 +/- 0.2 K). The critical exponent z nu=1.38 agrees rather well with experimental values in LaMn0.5Fe0.5O3 (z nu=1.0) [K. De , J. Appl. Phys. 99, 13908 (2006)] and the mean field theory (z nu=2.0) of Kirkpatrick and Sherrington [Phys. Rev. B 17, 4384 (1970)].
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页数:5
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