Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production

被引:7
作者
Wang Qiang [1 ,2 ]
Xu Rui [1 ]
Wang Xu-Sheng [1 ]
Liu Si-De [2 ]
Huang Yuan-Biao [1 ]
Cao Rong [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Fujian Normal Univ, Fuzhou 350007, Fujian, Peoples R China
关键词
metal-organic framework; mesopore; PCN-222; platinum nanoparticles; water splitting for hydrogen production; COMPOSITES; STABILITY; EVOLUTION; CATALYSTS; POLYMERS; CLUSTERS;
D O I
10.11862/CJIC.2017.240
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Herein, Pt NPs of ca. 2.5 nm incorporated inside the mesopores of porphyrin-based MOF PCN-222, denoted as Pt@PCN-222, were prepared using double-solvent method followed by visible-light reduction. The obtained mesoporous MOF composite Pt@PCN-222 can effectively adsorb visible-light to promote the water splitting for hydrogen production, which gives a H-2 yield of 253 mu mol. g(-1).h(-1).
引用
收藏
页码:2038 / 2044
页数:7
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