High pressure NMR flow cell for the in situ study of homogeneous catalysis

被引：23
|
作者：
Iggo, JA [1 ]
Shirley, D [1 ]
Tong, NC [1 ]
机构：
[1] Univ Liverpool, Donnan & Robert Robinson Labs, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 10期
关键词：
D O I：
10.1039/a806311g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel, convenient high pressure NMR flow cell for the in situ study of homogeneous catalysis capable of operating over the pressure range 1 to 200 bar and temperature range -40 to 175 degrees C is described; importantly, the inlet gas passes through the reaction solution ensuring good gas-solution mixing and maintaining the concentration of reacting gas in the solution thus preventing starvation of the reaction of gaseous reagents; the cell has been used to study the reaction of a rhodium-ruthenium bimetallic complex with CO.
引用
收藏
页码：1043 / 1045
页数：3
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