High pressure NMR flow cell for the in situ study of homogeneous catalysis

被引：23

作者：

Iggo, JA ^{[1
]}

Shirley, D ^{[1
]}

Tong, NC ^{[1
]}

机构：

[1] Univ Liverpool, Donnan & Robert Robinson Labs, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 10期

关键词：

D O I：

10.1039/a806311g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, convenient high pressure NMR flow cell for the in situ study of homogeneous catalysis capable of operating over the pressure range 1 to 200 bar and temperature range -40 to 175 degrees C is described; importantly, the inlet gas passes through the reaction solution ensuring good gas-solution mixing and maintaining the concentration of reacting gas in the solution thus preventing starvation of the reaction of gaseous reagents; the cell has been used to study the reaction of a rhodium-ruthenium bimetallic complex with CO.

引用

页码：1043 / 1045

页数：3

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