From supramolecular block copolymers to advanced nano-objects

被引：91
作者：
Gohy, JF
Lohmeijer, BGG
Schubert, US
机构：
[1] Eindhoven Univ Technol, Ctr Nanomat, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
[3] Catholic Univ Louvain, Unite Chim Mat Inorgan & Organ, B-1348 Louvain, Belgium
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2003年 / 9卷 / 15期
关键词：
block copolymers; micelles; nanotechnology; supramolecular chemistry; terpyridines;
D O I：
10.1002/chem.200204640
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of asymmetric bis-complexes, based on terpyridine ligands and ruthenium ions, is described as a powerful tool for the self-assembly of polymer blocks end-functionalized with terpyridine units. This is illustrated in this contribution for the synthesis of amphiphilic metallo-supramolecular block copolymers, which are further used to produce aqueous micelles. Finally, the reversibility of the supramolecular bond opens new avenues for the preparation and manipulation of these nano-objects.
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收藏
页码：3472 / 3479
页数：8
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