Temperature-induced reversible transformation between toroidal and cylindrical assemblies under shear flow

被引：38
作者：
Wang, Zhida [1 ,2 ]
Jiang, Wei [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
来源：
SOFT MATTER | 2010年 / 6卷 / 16期
基金：
中国国家自然科学基金;
关键词：
AMPHIPHILIC TRIBLOCK COPOLYMER; RING-SHAPED MORPHOLOGY; DIBLOCK COPOLYMERS; BLOCK-COPOLYMERS; DILUTE-SOLUTION; MICELLES; TRANSITIONS; DISPERSIONS;
D O I：
10.1039/c0sm00310g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A unique reversible transformation between toroidal and cylindrical assemblies was observed. Toroids can change to cylinders by elongation at higher temperature. Reversely, upon cooling rate these cylinders can form toroids through pathway of cylinder-sphere-vesicle-ring or the end-to-end connection.
引用
收藏
页码：3743 / 3746
页数：4
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