Alkaline-induced superhydrophilic/underwater superoleophobic polyacrylonitrile membranes with ultralow oil-adhesion for high-efficient oil/water separation

被引:169
作者
Zhang, Feng [1 ]
Gao, Shoujian [1 ]
Zhu, Yuzhang [1 ]
Jin, Jian [1 ]
机构
[1] Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, I Lab, Suzhou 215123, Peoples R China
基金
中国国家自然科学基金;
关键词
Superwetting material; Filtration membrane; Emulsion separation; Ultralow-oil-adhesion; WASTE-WATER TREATMENT; PVDF MEMBRANES; ULTRAFILTRATION; SURFACES; PURIFICATION; FABRICATION; EMULSIONS; PROGRESS; MESH; FLUX;
D O I
10.1016/j.memsci.2016.04.020
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Traditional polymer membranes prepared by phase inversion process have the problems of low flux and serious fouling when they were used for oil/water separation. In this work, an alkaline-induced phase inversion process is developed for the superhydrophilic/underwater superoleophobic polyacrylonitrile (PAN) ultrafiltration membrane. The as-prepared PAN ultrafiltration membrane could effectively separate oil-in-H2O emulsions with a high flux up to 2270 L/m(2) h bar and an extremely high rejection while the oil residual in filtrate after one-time separation is lower than 10 ppm. Also, the PAN membrane showed ultralow oil adhesion and antifouling properties and can be easily recycled with flux recovery ratio of 85%. This new PAN membrane has a great potential for treating oily wastewater. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:67 / 73
页数:7
相关论文
共 46 条
[1]   Porous materials for oil spill cleanup: A review of synthesis and absorbing properties [J].
Adebajo, MO ;
Frost, RL ;
Kloprogge, JT ;
Carmody, O ;
Kokot, S .
JOURNAL OF POROUS MATERIALS, 2003, 10 (03) :159-170
[2]   Destabilisation of oil-water emulsions and separation by dissolved air flotation [J].
Al-Shamrani, AA ;
James, A ;
Xiao, H .
WATER RESEARCH, 2002, 36 (06) :1503-1512
[3]   Oil Industry Wastewater Treatment with Fouling Resistant Membranes Containing Amphiphilic Comb Copolymers [J].
Asatekin, Ayse ;
Mayes, Anne M. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (12) :4487-4492
[4]   NEW RESULTS IN METAL-WORKING WASTE-WATER TREATMENT USING MEMBRANE TECHNOLOGY [J].
BELKACEM, M ;
MATAMOROS, H ;
CABASSUD, C ;
AURELLE, Y ;
COTTERET, J .
JOURNAL OF MEMBRANE SCIENCE, 1995, 106 (03) :195-205
[5]   Mineral-Coated Polymer Membranes with Superhydrophilicity and Underwater Superoleophobicity for Effective Oil/Water Separation [J].
Chen, Peng-Cheng ;
Xu, Zhi-Kang .
SCIENTIFIC REPORTS, 2013, 3
[6]   Efficient Wastewater Treatment by Membranes through Constructing Tunable Antifouling Membrane Surfaces [J].
Chen, Wenjuan ;
Su, Yanlei ;
Peng, Jinming ;
Zhao, Xueting ;
Jiang, Zhongyi ;
Dong, Yanan ;
Zhang, Yan ;
Liang, Yangui ;
Liu, Jiazhen .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (15) :6545-6552
[7]   A Polydimethylsiloxane (PDMS) Sponge for the Selective Absorption of Oil from Water [J].
Choi, Sung-Jin ;
Kwon, Tae-Hong ;
Im, Hwon ;
Moon, Dong-Il ;
Baek, David J. ;
Seol, Myeong-Lok ;
Duarte, Juan P. ;
Choi, Yang-Kyu .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (12) :4552-4556
[8]   Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials [J].
Chu, Zonglin ;
Feng, Yujun ;
Seeger, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (08) :2328-2338
[9]   Pumping through Porous Hydrophobic/Oleophilic Materials: An Alternative Technology for Oil Spill Remediation [J].
Ge, Jin ;
Ye, Yin-Dong ;
Yao, Hong-Bin ;
Zhu, Xi ;
Wang, Xu ;
Wu, Liang ;
Wang, Jin-Long ;
Ding, Hang ;
Yong, Ni ;
He, Ling-Hui ;
Yu, Shu-Hong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (14) :3612-3616
[10]  
Heiazi V., 2012, ADV MATER, V24, P5963