Iron binary and ternary coatings with molybdenum and tungsten

被引:28
作者
Yar-Mukhamedova, Gulmira [1 ]
Ved, Maryna [2 ]
Sakhnenko, Nikolay [2 ]
Karakurkchi, Anna [2 ]
Yermolenko, Iryna [2 ]
机构
[1] Al Farabi Kazakh Natl Univ, Inst Expt & Theoret Phys, Al Farabi Ave 71, Alma Ata 050038, Kazakhstan
[2] Natl Tech Univ, Kharkov Polytech Inst, Kharkov, Ukraine
关键词
Fe-Mo and Fe-Mo-W alloys; Citrate electrolyte; Physical-mechanical properties; Electrodeposition; Corrosion resistance; Pulse electrolysis; CORROSION PROPERTIES; ALLOY COATINGS; FE; ELECTRODEPOSITION; DEPOSITION; RESISTANCE; NICKEL; COBALT;
D O I
10.1016/j.apsusc.2016.04.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrodeposition of Fe-Mo-W and Fe-Mo layers from a citrate solution containing iron(III) on steel and iron substrates is compared. The utilization of iron(III) compounds significantly improved the electrolyte stability eliminating side anodic redox reactions. The influence of concentration ratios and electrodeposition mode on quality, chemical composition, and functional properties of the alloys is determined. It has been found that alloys deposited in pulse mode have more uniform surface morphology and chemical composition and contain less impurities. Improvement in physical and mechanical properties as well as corrosion resistance of Fe-Mo and Fe-Mo-W deposits when compared with main alloy forming metals is driven by alloying components chemical passivity as well as by alloys amorphous structure. Indicated deposits can be considered promising materials in surface hardening technologies and repair of worn out items. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:346 / 352
页数:7
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