Cooperative dinitrogen capture by a diboraanthracene/samarocene pair

被引：13

作者：

Xu, Song ^{[1
]}

Essex, Laura A. ^{[2
]}

Nguyen, Joseph Q. ^{[1
]}

Farias, Phillip ^{[2
]}

Ziller, Joseph W. ^{[1
]}

Harman, W. Hill ^{[2
]}

Evans, William J. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

[2] Univ Calif Irvine, Dept Chem, Riverside, CA 92521 USA

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 42期

基金：

美国国家科学基金会;

关键词：

CRYSTALLOGRAPHIC CHARACTERIZATION; CRYSTAL-STRUCTURE; COMPLEX; ACTIVATION; REACTIVITY; BOND; N-2;

D O I：

10.1039/d1dt03220h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of a boron Lewis acid and a decamethyl-samarocene, specifically 9,10-Me-2-9,10-diboraanthracene with (C5Me5)(2)Sm-II(THF)(2), in toluene leads to cooperative reductive capture of N-2. The product crystallizes as the salt, [(C5Me5)(2)Sm-III(THF)(2)][(C5Me5)(2)Sm-III(eta(2)-N2B2C14H14)], 1, which formally is comprised of an (N[double bond, length as m-dash]N)(2-) moiety sandwiched between a [(C5Me5)(2)Sm-III](1+) metallocene cation and the diboraanthracene ditopic Lewis acid.

引用

收藏

页码：15000 / 15002

页数：3

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