Stereoselective synthesis of (+)-1-deoxyaltronojirimycin

被引：2

作者：

Righi, Giuliana ^{[1
]}

Mandic, Emanuela ^{[2
]}

Tirotta, Ilaria ^{[2
]}

Naponiello, Gaia Clara Mercedes ^{[2
]}

Sappino, Carla ^{[2
]}

Marucci, Cristina ^{[2
]}

Tomei, Michela ^{[2
]}

Bovicelli, Paolo ^{[1
]}

机构：

[1] Univ Roma La Sapienza, CNR IBPM, Dept Chem, Rome, Italy

[2] Univ Roma La Sapienza, Dept Chem, Rome, Italy

来源：

NATURAL PRODUCT RESEARCH | 2016年 / 30卷 / 14期

关键词：

Iminosugar; stereoselective synthesis; heterocycles; dihydroxylation; 1-deoxyaltronojirimycin; ASYMMETRIC-SYNTHESIS; 1-DEOXYNOJIRIMYCIN; ACID; 1-DEOXYALTRONOJIRIMYCIN; DIHYDROXYLATION; TRANSFORMATIONS; DERIVATIVES; OXIDATION; ANALOGS; ESTER;

D O I：

10.1080/14786419.2015.1131983

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A stereocontrolled, facile and high-yield approach for producing (+)-altroDNJ, has been developed starting from the inexpensive commercial cis 2-butene-1,4-diol. Sharpless epoxidation and a subsequent dihydroxylation were used for the introduction of all stereocentres; finally, the ring closure under basic conditions afforded the piperidine heterocycle. [GRAPHICS] .

引用

页码：1655 / 1660

页数：6

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