Liquid Catholyte Molecules for Nonaqueous Redox Flow Batteries

被引：147

作者：

Huang, Jinhua ^{[1
]}

Cheng, Lei ^{[2
]}

Assary, Rajeev S. ^{[2
]}

Wang, Peiqi ^{[1
]}

Xue, Zheng ^{[1
]}

Burrell, Anthony K. ^{[1
]}

Curtiss, Larry A. ^{[2
]}

Zhang, Lu ^{[1
]}

机构：

[1] Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

来源：

ADVANCED ENERGY MATERIALS | 2015年 / 5卷 / 06期

关键词：

catholytes; electrochemistry; nonaqueous redox flow batteries; redox-active molecules; rational molecular design; ION; ELECTROLYTES; OVERCHARGE; SHUTTLE; PROTECTION; DIFFUSION; PROGRESS; CELL;

D O I：

10.1002/aenm.201401782

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of dimethoxybenzene-based catholyte molecules, which are electrochemically reversible at high potential (4.0 V vs Li/Li+) and in the form of liquid, is developed. The liquid nature offers the molecules the possibility of being a solo or co-solvent for nonaqueous redox flow batteries. This could dramatically improve the energy density. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页数：6

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