Temperature dependent dielectric properties and AC conductivity studies on titanium niobium oxide (TiNb2O7) thin films

The dielectric properties of TiNb2O7 (TNO) thin films are studied in Metal-Insulator-Metal configuration (Au/TiNb2O7/Pt) devices. The temperature dependence of the dielectric dispersion and the AC conductivity behavior is strongly dependent on TNO thin film thickness. Low thickness (similar to 236 nm) films shows considerably less variation with temperatures than their thicker counterparts (similar to 480 nm). These behaviors are explained on physical basis - nearly constant loss (NCL) and Jonscher's Universal Dielectric Response (UDR). The TNO thin films show large dielectric constant ((similar to)59-73) and moderate dielectric loss (similar to 0.07-0.11). The AC conductivity values of the thin films lie in the range of about (10(-8) to 10(-9)) at 10 kHz. The thicker films show DC conductivity values which are thermally activated with an activation energy of about 0.44 eV. This is slightly higher (about 0.1 eV) than omega(p) in Jonscher's UDR response and this discrepancy is explained on the basis of mixed ionic electronic conduction in TNO thin films. The possible role of growth morphology in the dielectric response is also briefly mentioned.