Electrochemical oxidation of organic, organometallic, and coordination compounds. Polarization effect in radical cations

被引：8
|
作者：
Novikova, O. V. [1 ]
Kuznetsova, O. V. [1 ]
Egorochkin, A. N. [1 ]
机构：
[1] Russian Acad Sci, Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 09期
关键词：
D O I：
10.1134/S1070363207090174
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Half-wave potentials of electrochemical oxidation of 24 reaction series X-B-R-C depend on the inductive, resonance, and polarization effects of substituents X. The polarization effect was not taken into account previously. In X-B-R-C(center dot+) radical cations, the contribution of the polarization effect increases with decreasing size of bridge B linking X with the reaction center R-C and can reach 30%.
引用
收藏
页码：1601 / 1609
页数：9
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