Crystal packing in equilibrating systems:: A single crystal containing three isomers of CuCl(1-pyridin-2-yl-3-p-tolyl-thiourea)2

被引:27
作者
Lenthall, Joseph T.
Anderson, Kirsty M.
Smith, Stephen J.
Steed, Jonathan W.
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] BP Chemicals, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England
关键词
D O I
10.1021/cg070533k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The X-ray crystal structure of the labile copper(I) complex CuCl(1-pyridin-2-yi-3-p-tolyl-thiourea)(2) comprises three different isomers and has profound implications for work on the understanding and prediction of low-symmetry crystal packing. A chloroform co-crystal of one of these isomers is also reported along with a related compound of (6-methyl-benzothiazol-2-yl)pyridin-2-yl-amine.
引用
收藏
页码:1858 / 1862
页数:5
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