Synthesis of colloidal dispersions of NiAl, ZnAl, NiCr, ZnCr, NiFe, and MgFe hydrotalcite-like nanoparticles

被引：41

作者：

Bellezza, Francesca ^{[1
,2
]}

Nocchetti, Morena ^{[1
,2
]}

Posati, Tamara ^{[1
,2
]}

Giovagnoli, Stefano ^{[3
]}

Cipiciani, Antonio ^{[1
,2
]}

机构：

[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Perugia, CEMIN, I-06123 Perugia, Italy

[3] Univ Perugia, Dipartimento Chim & Tecnol Farmaco, I-06123 Perugia, Italy

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2012年 / 376卷

关键词：

Hydrotalcite-like compounds; Microemulsion; Nanoparticles; Aqueous dispersions; Colloidal stability; LAYERED DOUBLE HYDROXIDES; TRANSPARENT; FILMS; SIZE; PRECURSORS; CATALYSTS; HYDROGEN; ANIONS;

D O I：

10.1016/j.jcis.2012.02.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Colloidal aqueous dispersions of nanometric NiAl, ZnAl, NiCr, ZnCr, NiFe, and MgFe hydrotalcite-like compounds were prepared in a water/cetyltrimethylammonium bromide/n-butanol/isooctane microemulsion. Particle sizes were analyzed with different techniques, and the results confirm dimensions between 10 and 30 nm, except for ZnAl-HTlc (150-200 nm). A good colloidal stability of HTlc-NPs aqueous dispersions, investigated with DLS and Pz measurements, was obtained without the need for any stabilizing agent. SEM images clearly showed that the obtained HTlc posses a high tendency to spontaneously form homogeneous and dense stacking of plate-like HTlc crystals directly from aqueous solution, giving rise to the developing of functional materials in optical, electrical and magnetic fields. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：20 / 27

页数：8

共 56 条

[1] Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction-control of size and morphology [J].

Adachi-Pagano, M ;

Forano, C ;

Besse, JP .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (08) :1988-1993

[2] Zirconium phosphate nanoparticles from water-in-oil microemulsions [J].

Bellezza, Francesca ;

Cipiciani, Antonio ;

Costantino, Umberto ;

Marmottini, Fabio ;

Quotadamo, Maria Anna .

COLLOID AND POLYMER SCIENCE, 2006, 285 (01) :19-25

[3] Hydrotalcite-Like Nanocrystals from Water-in-Oil Microemulsions [J].

Bellezza, Francesca ;

Cipiciani, Antonio ;

Costantino, Umberto ;

Nocchetti, Morena ;

Posati, Tamara .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (18) :2603-2611

[4] Uniform fast growth of hydrotalcite-like compounds [J].

Benito, Patricia ;

Labajos, Francisco M. ;

Rives, Vicente .

CRYSTAL GROWTH & DESIGN, 2006, 6 (08) :1961-1966

[5] Layered double hydroxide stability. 2. Formation of Cr(III)-containing layered double hydroxides directly from solution [J].

Boclair, JW ;

Braterman, PS ;

Jiang, JP ;

Lou, SW ;

Yarberry, F .

CHEMISTRY OF MATERIALS, 1999, 11 (02) :303-307

[6] Nickel versus cobalt catalysts for hydrogen production by ethanol steam reforming: Ni-Co-Zn-Al catalysts from hydrotalcite-like precursors [J].

Busca, Guido ;

Costantino, Umberto ;

Montanari, Tania ;

Ramis, Gianguido ;

Resini, Carlo ;

Sisani, Michele .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (11) :5356-5366

[7] Clays and health: An introduction [J].

Carretero, Maria Isabel ;

Lagaly, Gerhard .

APPLIED CLAY SCIENCE, 2007, 36 (1-3) :1-3

[8] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

[9] Preparation and characterisation of hydrotalcite/carboxyadamantane intercalation compounds as fillers of polymeric nanocomposites [J].

Costantino, U. ;

Montanari, F. ;

Nocchetti, M. ;

Canepa, F. ;

Frache, A. .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (11) :1079-1086

[10]

Costantino U, 1998, EUR J INORG CHEM, P1439

← 1 2 3 4 5 6 →