The application of ultrasound to the synthesis of poly(organosilanes)

被引：12
作者：
Price, GJ
Patel, AM
机构：
[1] School of Chemistry, University of Bath, Bath, BA2 7AY, Claverton Down
来源：
EUROPEAN POLYMER JOURNAL | 1996年 / 32卷 / 11期
关键词：
D O I：
10.1016/S0014-3057(96)00084-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effect of carrying out Wurtz type polymerizations of dichlorodiorganosilanes to poly(organosilanes) under the influence of ultrasound has been investigated. The sonochemical reaction produced faster polymerizations and higher yields in a range of systems. Previous reports of modification of molecular weight distributions have been confirmed and the results used to elucidate the mechanism of the sonochemical enhancement. The control of molecular weight distributions by variation of the ultrasound properties is also illustrated. Copyright (C) 1996 Elsevier Science Ltd
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页码：1289 / 1295
页数：7
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