Quasicubic α-Fe2O3 nanoparticles embedded in TiO2 thin films grown by atomic layer deposition

被引:3
作者
Tamm, Aile [1 ]
Seinberg, Liis [2 ]
Kozlova, Jekaterina [1 ]
Link, Joosep [2 ]
Pikma, Piret [3 ]
Stern, Raivo [2 ]
Kukli, Kaupo [1 ,4 ]
机构
[1] Univ Tartu, Inst Phys, W Ostwaldi 1, EE-50411 Tartu, Estonia
[2] NICPB, Akad Tee 23, EE-12618 Tallinn, Estonia
[3] Univ Tartu, Inst Chem, Ravila 14A, EE-50411 Tartu, Estonia
[4] Univ Helsinki, Dept Chem, POB 55, FI-00014 Helsinki, Finland
基金
芬兰科学院;
关键词
Quasicubic alpha-Fe2O3 nanoparticles; Atomic layer deposition; Titanium oxide thin films; Magnetically susceptible materials; IRON-OXIDE NANOPARTICLES; RAMAN-SPECTROSCOPY;
D O I
10.1016/j.tsf.2016.06.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Monodispersed quasicubic alpha-Fe2O3 nanoparticles were synthesized from ferric nitrite(Fe(NO3)(3)), N, N-dimethyl formamide and poly(N-vinyl-2-pyrrolidone). Layers of nanoparticles were attached to HF-etched Si substrates by dip coating and subsequently embedded in thin titanium oxide films grown by atomic layer deposition from TiCl4 and H2O. The deposition of TiO2 onto Fe2O3 nanoparticles covered the nanoparticles uniformly and anatase phase of TiO2 was observed in Si/Fe2O3/TiO2 nanostructures. In Si/Fe2O3/TiO2 nanostructure magnetic domains, observable by magnetic force microscopy, were formed and these nanostructures implied ferromagnetic-like behavior at room temperature with the saturative magnetization and coercivity of 10 kA/m. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:445 / 449
页数:5
相关论文
共 38 条
[1]   Nanostructured solar cell by spray pyrolysis: Effect of titania barrier layer on the cell performance [J].
Acik, I. Oja ;
Katerski, A. ;
Mere, A. ;
Aarik, J. ;
Aidla, A. ;
Dedova, T. ;
Krunks, M. .
THIN SOLID FILMS, 2009, 517 (07) :2443-2447
[2]   Effect of annealing on the structure and magnetic properties of mechanically milled TiO2-Fe2O3 mixture [J].
Al-Saie, A. M. ;
Al-Shater, A. ;
Arekat, S. ;
Jaffar, A. ;
Bououdina, M. .
CERAMICS INTERNATIONAL, 2013, 39 (04) :3803-3808
[3]   Bifunctional TiO2 underlayer for α-Fe2O3 nanorod based photoelectrochemical cells: enhanced interface and Ti4+ doping [J].
Annamalai, Alagappan ;
Shinde, Pravin S. ;
Subramanian, Arunprabaharan ;
Kim, Jae Young ;
Kim, Jin Hyun ;
Choi, Sun Hee ;
Lee, Jae Sung ;
Jang, Jum Suk .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (09) :5007-5013
[4]   Effect of substrate-enhanced and inhibited growth on atomic layer deposition and properties of aluminum-titanium oxide films [J].
Arroval, Tonis ;
Aarik, Lauri ;
Rammula, Raul ;
Kruusla, Vegard ;
Aarik, Jaan .
THIN SOLID FILMS, 2016, 600 :119-125
[5]  
Brock T., 2010, European Coatings Handbook
[6]   Synthesis and magnetic properties of Fe2O3-TiO2 nano-composite particles using pulsed laser gas phase evaporation-liquid phase collecting method [J].
Chen, Suiyuan ;
Zhang, Yikun ;
Han, Weili ;
Wellburn, Daniel ;
Liang, Jing ;
Liu, Changsheng .
APPLIED SURFACE SCIENCE, 2013, 283 :422-429
[7]   Anatase nanocrystals coating on silica-coated magnetite: Role of polyacrylic acid treatment and its photocatalytic properties [J].
Cheng, J. P. ;
Ma, R. ;
Li, M. ;
Wu, J. S. ;
Liu, F. ;
Zhang, X. B. .
CHEMICAL ENGINEERING JOURNAL, 2012, 210 :80-86
[8]   On-line analysis using Raman spectroscopy for process control during the manufacture of titanium dioxide [J].
Clegg, IM ;
Everall, NJ ;
King, B ;
Melvin, H ;
Norton, C .
APPLIED SPECTROSCOPY, 2001, 55 (09) :1138-1150
[9]  
De Temmerman ML, 2014, NANOMEDICINE-UK, V9, P1363, DOI [10.2217/nnm.13.88, 10.2217/NNM.13.88]
[10]   Oxidation and Reduction of Iron-Titanium Oxides in Chemical Looping Combustion: A Phase-Chemical Description [J].
den Hoed, P. ;
Luckos, A. .
OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES, 2011, 66 (02) :249-263