Crystal Structure, and Luminescent Property of the Zinc(II) Complex Based on 2-Hydroxynaphthaldehyde

被引：1

作者：

Dong, X. -Y. ^{[1
]}

Zheng, Sh. -Sh. ^{[1
]}

Dong, Y. -J. ^{[1
]}

Meng, J. -L. ^{[1
]}

Dong, W. -K. ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou, Gansu, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 04期

关键词：

Salamo-type bisoxime compound; Zn(II) complex; synthesis; crystal structure; luminescent property; LANTHANIDE COMPLEXES; LIGAND SYNTHESIS; SALEN LIGANDS; FLUORESCENCE; METAL; COBALT(II); TETRAOXIME; OXIME;

D O I：

10.1134/S0022476618040340

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new trinuclear Zn(II) complex [(ZnL)(2)(OAc)(2)Zn]<bold></bold>2THF with a Salamo-type bisoxime ligand H2L (2,2-[ethylenedioxybis(nitrilomethylidyne)]dinaphthol) is synthesized and structurally characterized. The luminescence study demonstrates that the Salamo-type ligand exhibits a good antennae effect with respect to the Zn(II) ion due to an efficient intersystem crossing and ligand-to-metal energy transfer. From a more general perspective, this work opens interesting perspectives for the development of efficient luminescent stains to obtain a novel luminescent Zn(II) complex with Salamo-type derivatives.

引用

页码：981 / 987

页数：7

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