Synthesis, reaction chemistry and electrochemical behaviour of (η5-C5H4SiMe3)2Hf(CCFc)2

被引：26

作者：

Back, S

Rheinwald, G

Zsolnai, L

Huttner, G

Lang, H

机构：

[1] Tech Univ Chemnitz, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 563卷 / 1-2期

关键词：

hafnocene; ferrocene; alkyne; nickelcarbonyl;

D O I：

10.1016/S0022-328X(98)00556-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Hf]Cl-2 (1) {[Hf] = (eta(5)-C5H4SiMe3)(2)Hf} reacts with 2.0 mol equiv of LiC=CFc (2) [Fc=(eta(5)-C5H4)(eta(5)-C5H5)Fe] to produce [Hf](C=CFc)(2) (3). Treatment of 3 with Ni(CO)(4); (4) affords {[Hf](C=CFc)(2)}Ni(CO) (5). The electrochemical behaviour of 3 is discussed. The X-ray structure analysis of 3 is reported; 3 crystallizes in the orthorhombic space group Pnna with cell constants a = 11.431(2), b = 16.521(2), c = 19.130(2) Angstrom V, = 3612.7(9) Angstrom(3); and Z = 4. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：73 / 79

页数：7

共 101 条

[1] SYNTHESIS OF FERROCENYLACETYLENES
ABRAM, TS
WATTS, WE
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1976, 6 (01): : 31 - 53
[2] [Anonymous], ANGEW CHEM
[3] SILYLMETHYL AND RELATED COMPLEXES .5. METALLOCENE BIS(TRIMETHYLSILYL)METHYLS AND BENZHYDRYLS OF EARLY TRANSITION-METALS [M(ETA5-C5H5)2R](M = TI OR V) AND [META5-C5H5)2(X)R](M = ZR OR HF AND X = CL OR R), AND CRYSTAL AND MOLECULAR STRUCTURES OF [M(ETA5-C5H5)2(CHPH2)2] (M = ZR OR HF)
ATWOOD, JL
BARKER, GK
HOLTON, J
HUNTER, WE
LAPPERT, MF
PEARCE, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) : 6645 - 6652
[4] C2-bridged titanocene-ferrocenyl complexes:: Synthesis, reaction chemistry, and electrochemical behavior
Back, S
Pritzkow, H
Lang, H
[J]. ORGANOMETALLICS, 1998, 17 (01) : 41 - 44
[5] BIS(ETA-5-CYCLOPENTADIENYL)HAFNIUM COMPLEXES CONTAINING SIGMA-BONDED ALKYNYL GROUPS
BARRAL, MC
JIMENEZ, R
SANTOS, A
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1982, 63 (02): : 257 - 260
[6] BARTIK T, 1996, ANGEW CHEM INT EDIT, V35, P968
[7] METHODS FOR THE SYNTHESIS OF MU-HYDROCARBON TRANSITION-METAL COMPLEXES WITHOUT METAL-METAL BONDS
BECK, W
NIEMER, B
WIESER, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (07) : 923 - 949
[8] NEW BIMETALLIC HYDROCARBON-BRIDGED COMPLEXES BY NUCLEOPHILIC-ATTACK OF CARBONYLMETALLATES TO COORDINATED UNSATURATED-HYDROCARBONS
BECK, W
NIEMER, B
BREIMAIR, J
HEIDRICH, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (01) : 79 - 83
[9] BECK W, 1993, ANGEW CHEM, V105, P969
[10] ALPHA-HALOFERROCENES - SYNTHESIS OF FERROCENYLACETYLENE
BENKESER, RA
FITZGERALD, WP
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (10) : 4179 - &

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