Densities and excess molar volumes of the ternary mixture (1-butanol plus n-hexane plus 1-chlorobutane) at 298.15 and 313.15 K. Application of the ERAS model

被引:14
作者
Dominguez, M [1 ]
Artigas, H [1 ]
Santafe, J [1 ]
Mainar, A [1 ]
Urieta, JS [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, Area Quim Fis,Secc Quim, E-50009 Zaragoza, Spain
关键词
densities; excess volumes; mixture; ERAS model; 1-butanol; n-hexane; 1-chlorobutane;
D O I
10.1016/S0378-3812(97)00293-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities of the liquid mixtures (n-hexane + 1-chlorobutane) and (1-butanol + n-hexane + 1-chlorobutane) have been measured by the vibrating tube technique at 298.15 K and 313.15 K. With these densities, excess molar volumes were calculated. An extended version of the so-called ERAS model has been used for describing VE Of the complete ternary system at 298.15 K. Qualitatively the ERAS-model gives an adequate representation of this system, being similar the shapes of both the experimental and the predicted curves. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:115 / 128
页数:14
相关论文
共 17 条
[1]   THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].
ABE, A ;
FLORY, PJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1838-&
[2]  
[Anonymous], 1986, PHYS PROPERTIES METH
[3]   EXCESS VOLUMES OF (AN ALKANOL PLUS A HALOALKANE) AT THE TEMPERATURES 298.15-K AND 313.15-K [J].
ARTIGAS, H ;
SANTAFE, J ;
LOPEZ, MC ;
ROYO, FM ;
URIETA, JS .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (11) :1403-1407
[4]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[6]   Densities and viscosities of the ternary mixtures 1-butanol plus 1-chlorobutane plus 1-butylamine and 2-methyl-1-propanol plus 1-chlorobutane plus 1-butylamine at 298.15 K [J].
Dominguez, M ;
Rodriguez, S ;
Lopez, MC ;
Royo, FM ;
Urieta, JS .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (01) :37-42
[7]   Excess molar volumes of the ternary mixture {x(1)CH(3)(CH2)(3)OH+x(2)CH(3)(CH2)(4)CH3+(1-X(1)-X(2))CH3(CH2)(3)NH2} at temperatures of 298.15 K and 313.15 K [J].
Dominguez, M ;
Cea, P ;
Lafuente, C ;
Royo, FM ;
Urieta, JS .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1996, 28 (07) :779-786
[8]   STATISTICAL THERMODYNAMICS OF CHAIN MOLECULE LIQUIDS .I. EQUATION OF STATE FOR NORMAL PARAFFIN HYDROCARBONS [J].
FLORY, PJ ;
ORWOLL, RA ;
VRIJ, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (17) :3507-+
[9]   NEW APPLICATIONS OF THE ERAS MODEL - THERMODYNAMICS OF AMINE+ALKANE AND ALCOHOL+AMINE MIXTURES [J].
FUNKE, H ;
WETZEL, M ;
HEINTZ, A .
PURE AND APPLIED CHEMISTRY, 1989, 61 (08) :1429-1439
[10]   EXCESS VOLUMES OF BINARY 1-ALKANOL HEXANE MIXTURES AT TEMPERATURES BETWEEN 283.15-K AND 323.15-K [J].
HEINTZ, A ;
SCHMITTECKER, B ;
WAGNER, D ;
LICHTENTHALER, RN .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (04) :487-492