THE KINETIC STUDY ON Fe2+/PS SYSTEM IN REMOVING BPA IN AQUEOUS SOLUTION

被引:0
作者
Song, Tiehong [1 ]
Wei, Hongyan [1 ]
Chen, Lizhu [1 ]
Li, Shujie [1 ]
Gao, Yanjiao [2 ]
机构
[1] Changchun Univ Architecture & Civil Engn, Urban Construct Coll, Changchun 130000, Peoples R China
[2] Liaoning Univ Technol, Coll Civil Engn & Architecture, Jinzhou City 121001, Peoples R China
来源
FRESENIUS ENVIRONMENTAL BULLETIN | 2022年 / 31卷 / 08期
基金
中国国家自然科学基金;
关键词
Sulfate radicals; ferrous ion; Bisphenol A; hydroxyl radicals; advanced oxidation processes (AOPs); BISPHENOL-A BPA; DEGRADATION; PERSULFATE; OXIDATION; WATER; ACTIVATION; HEAT; MECHANISM; FE(III);
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, the process of ferrous ion activating persulfate (PS) was assigned to degrade bisphonel A (EPA) in aqueous solution. The factors affecting the activation of PS by ferrous iron and the degradation rate of BPA have been systematically studied. It was found that the amount of the catalyst ferrous ion, the concentration of the oxidant BPA, the concentration of the substrate EPA, the initial pH value and the initial reaction temperature have important influences on the degradation of BPA in Fe2+/PS system. The best conditions for this experiment was determined as: [FeSO4](0)=0.1 g/L, [PS](0)=0.4mM, and pH(0)=5.0. Increasing the concentration of the substrate BPA led to the reduction of the removal rate of BPA. The increase in temperature utilized the progress of catalytic reaction and the degradation of BPA, and the degradation of BPA could reach 96.7% at 70 degrees C.
引用
收藏
页码:8119 / 8124
页数:6
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