Three-Component Acylation/Peroxidation of Alkenes through Visible-Light Photocatalysis

被引：4
|
作者：
Zhao, Dengyang [1 ]
Pan, Yingjie [1 ]
Chen, Xiaoyun [2 ]
Han, Ying [1 ]
Yan, Chaoguo [1 ]
Shi, Yaocheng [1 ]
Hou, Hong [1 ]
Zhu, Shaoqun [1 ]
机构：
[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212005, Jiangsu, Peoples R China
来源：
CHEMISTRYSELECT | 2021年 / 6卷 / 40期
基金：
中国国家自然科学基金;
关键词：
beta-peroxyketones; three-component reaction; photoredox catalysis; indole derivatives; CARBONYLATION-PEROXIDATION; STYRENE DERIVATIVES; ALDEHYDES; CYCLIZATIONS;
D O I：
10.1002/slct.202103431
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A three-component acylation/peroxidation of alkenes through visible-light photocatalysis was described. The acyl radical was generated by a hydrogen atom transfer process and enabled the radical addition and peroxidation. Various indole-3-carbaldehyde and styrene derivatives were subjected to the current visible light photochemical conditions, delivering beta-peroxy-ketones in moderate to good isolated yields.
引用
收藏
页码：10834 / 10838
页数：5
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