Volumetric Properties of Some Aliphatic Mono- and Dicarboxylic Acids in Water at 298.15 K

被引：9
|
作者：
Bald, Adam [1 ]
Kinart, Zdzislaw [1 ]
机构：
[1] Univ Lodz, Dept Phys Chem Solut, PL-90236 Lodz, Poland
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2011年 / 40卷 / 01期
关键词：
Carboxylic acid; Apparent molar volume; Water; APPARENT MOLAR VOLUMES; AQUEOUS-SOLUTIONS; HEAT-CAPACITIES; CARBOXYLIC-ACIDS; ORGANIC-ACIDS; SODIUM-SALTS; THERMODYNAMICS; ELECTROLYTES; DISSOCIATION; TEMPERATURES;
D O I：
10.1007/s10953-010-9621-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The apparent molar volumes, V-phi, of two series of homologous aliphatic carboxylic acids, H(CH2)(n)COOH [n = 0-5] and (CH2)(n)(COOH)(2) [n = 0-5], were determined in dilute aqueous solutions by density measurements at T = 298.15 K. Densities were measured using a vibrating-tube densimeter (DMA 5000, Anton Paar, Austria) at T = 298.15 K. These results were used to calculate the apparent molar volumes of each solute over the concentration range 0.0050 <= m/(mol.kg(-1)) <= 0.3000. Values of the apparent molar volumes of undissociated acids V-phi(u)(0) were also calculated. The variation of V-phi(u)(0)(u) was determined as a function of the aliphatic chain length of the studied carboxylic acids.
引用
收藏
页码：1 / 16
页数：16
相关论文
共 50 条
  • [1] Volumetric Properties of Some Aliphatic Mono- and Dicarboxylic Acids in Water at 298.15 K
    Adam Bald
    Zdzisław Kinart
    Journal of Solution Chemistry, 2011, 40 : 1 - 16
  • [2] Volumetric studies of aqueous solutions of monosodium salts of some aliphatic dicarboxylic acids at 298.15 K. A new method of data analysis
    Bald, Adam
    Kinart, Zdzislaw
    Tomas, Renato
    JOURNAL OF MOLECULAR LIQUIDS, 2013, 178 : 94 - 98
  • [3] Pyrolytic decarboxylation of some derivatives or perfluorinated mono- and dicarboxylic acids
    Lebedev, NV
    Berenblit, VV
    Starobin, YK
    Gubanov, VA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2005, 78 (10) : 1640 - 1645
  • [4] Pyrolytic Decarboxylation of Some Derivatives of Perfluorinated Mono- and Dicarboxylic Acids
    N. V. Lebedev
    V. V. Berenblit
    Yu. K. Starobin
    V. A. Gubanov
    Russian Journal of Applied Chemistry, 2005, 78 : 1640 - 1645
  • [5] Isoquercitrin Esters with Mono- or Dicarboxylic Acids: Enzymatic Preparation and Properties
    Vavrikova, Eva
    Langschwager, Fanny
    Jezova-Kalachova, Lubica
    Krenkova, Alena
    Mikulova, Barbora
    Kuzma, Marek
    Kren, Vladimir
    Valentova, Katerina
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2016, 17 (06):
  • [6] CHEMISTRY OF PERFLUORINATED AROMATIC MONO- AND DICARBOXYLIC ACIDS
    SARTORI, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (11) : 994 - &
  • [7] Tricyclohexylphosphine in Reactions with Unsaturated Mono- and Dicarboxylic Acids
    Bakhtiyarova, Yu. V.
    Bondar, M. S.
    Galkina, I. V.
    Galkin, V. I.
    UCHENYE ZAPISKI KAZANSKOGO UNIVERSITETA-SERIYA ESTESTVENNYE NAUKI, 2008, 150 (01): : 42 - 55
  • [8] Acylation of Convolvine by Anhydrides of Mono- and Dicarboxylic Acids
    D. B. Kadirova
    N. I. Mukarramov
    S. F. Aripova
    Kh. M. Shakhidoyatov
    Chemistry of Natural Compounds, 2014, 50 : 576 - 577
  • [9] Acylation of Convolvine by Anhydrides of Mono- and Dicarboxylic Acids
    Kadirova, D. B.
    Mukarramov, N. I.
    Aripova, S. F.
    Shakhidoyatov, Kh. M.
    CHEMISTRY OF NATURAL COMPOUNDS, 2014, 50 (03) : 576 - 577
  • [10] Apparent molal volumes of sodium salts of some aliphatic carboxylic acids in water at 298.15 K
    Kinart, Zdzislaw
    Bald, Adam
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2011, 49 (03) : 366 - 378
12345