Structural understanding of a molecular material that is accessed only by a solid-state desolvation process: The scope of modern powder X-ray diffraction techniques

被引:61
|
作者
Guo, F [1 ]
Harris, KDM [1 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
关键词
D O I
10.1021/ja050733p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Many molecular materials cannot be prepared as a "pure" (nonsolvate) crystalline phase by conventional crystal growth from solution due to the facile formation of solvate structures. In such cases, it may be possible to obtain the pure phase by a solid-state desolvation process, although such processes are generally associated with loss of crystal integrity, yielding a microcrystalline powder of the pure phase. This paper demonstrates the utility of modern powder X-ray diffraction techniques for obtaining structural understanding in such cases, focusing on a particular member of a structural family that is of wider relevance within the context of crystal engineering and design. Copyright © 2005 American Chemical Society.
引用
收藏
页码:7314 / 7315
页数:2
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