Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2+2]-Photocycloaddition

被引：24

作者：

Ahuja, Sapna ^{[1
,2
]}

Raghunathan, Ramya ^{[3
]}

Kumarasamy, Elango ^{[3
]}

Jockusch, Steffen ^{[3
]}

Sivaguru, Jayaraman ^{[1
,2
]}

机构：

[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA

[2] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA

[3] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 41期

基金：

美国国家科学基金会;

关键词：

NON-BIARYL ATROPISOMERS; PATERNO-BUCHI REACTION; ENE REACTIONS; ORGANIC-SYNTHESIS; SINGLET OXYGEN; PHOTOCYCLOADDITION;

D O I：

10.1021/jacs.8b08100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.

引用

页码：13185 / 13189

页数：5

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