A reversible metal-ligand bond break associated to a spin-crossover

被引：65

作者：

Guionneau, Philippe ^{[1
]}

Le Gac, Frederic ^{[1
]}

Kaiba, Abdellah ^{[1
]}

Costa, Jose Sanchez ^{[1
]}

Chasseau, Daniel ^{[1
]}

Letard, Jean-Francois ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 36期

关键词：

D O I：

10.1039/b707836f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [(FeL)-L-II(CN)(2)]center dot H2O complex,dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1] octadeca-1(18), 2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta- coordinate high spin state to a hexa-coordinate low spin state.

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页码：3723 / 3725

页数：3

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