Synthesis, Crystal Structure, and Properties of Two 2D Lamella Coordination Polymers Generated from Unsymmetrically Carboxylate Bridging Ligand

被引：7

作者：

Li, Xiao-Ling ^{[1
]}

Liu, Guang-Zhen ^{[1
]}

Xin, Ling-Yun ^{[1
]}

Li, Gui-Lian ^{[1
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 06期

基金：

中国国家自然科学基金;

关键词：

2D layer; 5-ethyl-pyridine-2; 3-dicarboxylic acid; homophthalic acid; magnetic property; METAL-ORGANIC FRAMEWORKS; GUEST ADSORPTION; MODULATION; SHRINKING; UNITS; LAYER;

D O I：

10.1080/15533174.2013.769595

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly between simple unsymmetrical ligands, such as h(2)epda (5-ethyl-pyridine-2,3-dcarboxylic acid) and H(2)hmph(homophthalic acid) and two transition metals produce two new 2D lamella coordination polymers [Cu(hedpa)(2)](n) 1 and [Co(hmph)(bpe)](n) 2 (bpe = 1,2-di(4-pyridyl)ethylene), respectively. The 2D lamella structure of 2 features hmph-bridged binuclear cobalt(II) chains joined by less flexible trans-bpe ligands, whereas the 2D layer of 1 manifests that unsymmetrical ligand h(2)epda directly bridges mononuclear copper(II) running along the bc plane. The thermogravimetric (TG) reveal that both compounds are stable. Magnetic measurements show that complex 2 exhibits global metamagnetic behaviors.

引用

页码：914 / 920

页数：7

共 21 条

[1] Synthetic and magnetic studies of a dodecanuclear cobalt wheel [J].

Brechin, EK ;

Cador, O ;

Caneschi, A ;

Cadiou, C ;

Harris, SG ;

Parsons, S ;

Vonci, M ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 2002, (17) :1860-1861

[2] Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences [J].

Ferey, Gerard ;

Serre, Christian .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1380-1399

[3] A mixed-valence Co7 single-molecule magnet with C3 symmetry [J].

Ferguson, Alan ;

Parkin, Andrew ;

Sanchez-Benitez, Javier ;

Kamenev, Konstantin ;

Wernsdorfer, Wolfgang ;

Murrie, Mark .

CHEMICAL COMMUNICATIONS, 2007, (33) :3473-3475

[4] A novel metal-organic framework displaying reversibly shrinking and expanding pore modulation [J].

Li, Xiao-Ling ;

Liu, Guang-Zhen ;

Xin, Ling-Yun ;

Wang, Li-Ya .

CRYSTENGCOMM, 2012, 14 (18) :5757-5760

[5] Ancillary ligand-mediated syntheses and fluorescence properties of zinc(II) complexes based on flexible benzene dicarboxylic acid [J].

Liu, Guang-Zhen ;

Xin, Ling-Yun ;

Wang, Li-Ya .

CRYSTENGCOMM, 2011, 13 (08) :3013-3020

[6] Expanding and shrinking porous modulation based on pillared-layer coordination polymers showing selective guest adsorption [J].

Maji, TK ;

Uemura, K ;

Chang, HC ;

Matsuda, R ;

Kitagawa, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (25) :3269-3272

[7] Structural diversity in a series of metal-organic frameworks (MOFs) composed of divalent transition metals, 4,4′-bipyridine and a flexible carboxylic acid [J].

Pachfule, Pradip ;

Panda, Tamas ;

Dey, Chandan ;

Banerjee, Rahul .

CRYSTENGCOMM, 2010, 12 (08) :2381-2389

[8] Urea Metal-Organic Frameworks as Effective and Size-Selective Hydrogen-Bond Catalysts [J].

Roberts, John M. ;

Fini, Branden M. ;

Sarjeant, Amy A. ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Scheidt, Karl A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (07) :3334-3337

[9] Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks [J].

Rowsell, JLC ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) :1304-1315

[10]

Sheldrick, 1997, PROGRAM SIEMENS AREA

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