Telomerization of butadiene with pentoses in water:: selective etherifications

被引：46

作者：

Estrine, B ^{[1
]}

Bouquillon, S ^{[1
]}

Hénin, F ^{[1
]}

Muzart, J ^{[1
]}

机构：

[1] Univ Reims, Unite Mixte Rech React Select & Applicat, CNRS, F-51687 Reims, France

来源：

GREEN CHEMISTRY | 2005年 / 7卷 / 04期

关键词：

D O I：

10.1039/b418236g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conditions have been developed to achieve the palladium catalysed telomerization of butadiene with L-arabinose and D-xylose in aqueous medium. The success of the reaction requires the presence of a tertiary amine as promoter with a catalytic system based on Pd-TPPTS. The etherification first occurs on the anomeric hydroxyl and, depending on the amine used, a second etherification leads to formation of the diether.

引用

页码：219 / 223

页数：5

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