Formation of ZnMn2O4 Ball-in-Ball Hollow Microspheres as a High-Performance Anode for Lithium-Ion Batteries

被引：621
|
作者：
Zhang, Genqiang [1 ,2 ]
Yu, Le [2 ]
Wu, Hao Bin [2 ]
Hoster, Harry E. [1 ]
Lou, Xiong Wen [1 ,2 ]
机构：
[1] TUM CREATE Ctr Electromobil, Singapore 637459, Singapore
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
来源：
ADVANCED MATERIALS | 2012年 / 24卷 / 34期
基金：
新加坡国家研究基金会;
关键词：
STORAGE PROPERTIES; PRECURSOR ROUTE; SPHERES; CAPACITY; CELLS; FABRICATION; NANOWIRES;
D O I：
10.1002/adma.201201779
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel ZnMn 2O 4 ball-in-ball hollow microspheres are fabricated by a facile two-step method involving the solution synthesis of ZnMn-glycolate hollow microspheres and subsequent thermal annealing in air. When evaluated as an anode material for lithium-ion batteries, these ZnMn 2O 4 ball-in-ball hollow microspheres show significantly enhanced electrochemical performance with high capacity, excellent cycling stability and good rate capability. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4609 / 4613
页数：5
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