The localized-to-delocalized transition in mixed-valence chemistry

被引：956

作者：

Demadis, KD

Hartshorn, CM

Meyer, TJ

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[2] Univ N Carolina, Dept Chem, Venable Lab, Chapel Hill, NC 27599 USA

[3] Univ N Carolina, Dept Chem, Kenan Lab, Chapel Hill, NC 27599 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 09期

关键词：

D O I：

10.1021/cr990413m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The analysis and catagorization of the transition between localization and delocalization in ligand-bridged, mixed-valence molecules were discussed. Transition metal complexes were used. Results showed that the molecules reveal the extraordinarily subtle nuances that can be displayed by real mixed-valence molecules in the localized-to-delocalized transition. A new class of mixed-valence molecules were also found.

引用

页码：2655 / 2685

页数：31

共 311 条

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