Physical and Mechanical Properties of Different Ratios of Palm Oil-Based Alkyd/Epoxy Resins

被引:20
作者
Issam, A. M. [1 ]
Khizrien, A. K. Nurul [1 ]
Mazlan, I. [1 ]
机构
[1] Univ Sains Malaysia, Sch Ind Technol, George Town 11800, Malaysia
关键词
Adhesion; Hardness; Resins; Thermal properties; COATINGS;
D O I
10.1080/03602559.2011.578289
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Epoxy resin was prepared by reaction of bisphenol-A and epichlorohydrin. The alkyd resin was prepared by reaction of palm oil as mono fatty acid, glycerol, and phthalic anhydride. The two resins were mixed in ratios of epoxy/alkyd of 50:50, 60:40, 70:30, and 80:20 and showed excellent dispersion. The physical and mechanical properties were determined using scanning electron microscopy (SEM) and FT-IR, viscosity, water resistance, chemical resistance, hardness, impact strength, and adhesion. Thermal properties were analyzed by thermogravimetric analysis. The coating prepared using 80:20 epoxy to alkyd resin exhibited higher hardness but lower impact strength than coatings with lower ratios.
引用
收藏
页码:1256 / 1261
页数:6
相关论文
共 24 条
[1]  
[Anonymous], 1994, D163990 ASTM, V1, P273
[2]  
[Anonymous], 1991, ANN BOOK ASTM STAND, V6, P268
[3]  
Azam M., 2006, INT J APPL CHEM, V2, P13
[4]  
BAJPAI M, 2000, Pigm Resin Technol, V29, P82, DOI DOI 10.1108/03699420010317825
[5]   EPOXY-RESINS FROM 1980 TO DATE .1. [J].
BHATNAGAR, MS .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1993, 32 (1-2) :53-113
[6]   Prediction of long term strength of adhesively bonded steel/epoxy joints in sea water [J].
Bordes, M. ;
Davies, P. ;
Cognard, J. -Y. ;
Sohier, L. ;
Sauvant-Moynot, V. ;
Galy, J. .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2009, 29 (06) :595-608
[7]   STUDY OF THE MISCIBILITY OF POLY(VINYL PYRIDINES) WITH POLY(VINYL ACETATE), POLY(VINYL ALCOHOL) AND THEIR COPOLYMERS [J].
CESTEROS, LC ;
ISASI, JR ;
KATIME, I .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1994, 32 (02) :223-230
[8]  
Ceylan K, 2005, THESIS U MIDDLE E TE, P19
[9]  
DiStasio J.I, 1982, CHEM TECHNOLOGY REV
[10]   Alkyd-epoxy blends as multipurpose coatings [J].
Dutta, N ;
Karak, N ;
Dolui, SK .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 100 (01) :516-521