Fabrication of a flower-like Cu(OH)2 nanoarchitecture and its composite with CNTs for use as a supercapacitor electrode

被引:14
作者
Shakir, Imran [1 ]
Almutairi, Zeyad [1 ,2 ,3 ]
Shar, Sahar Saad [1 ,4 ]
Nafady, Ayman [5 ]
机构
[1] King Saud Univ, Coll Engn, Sustainable Energy Technol Ctr, POB 800, Riyadh 11421, Saudi Arabia
[2] King Saud Univ, Coll Engn, Mech Engn Dept, POB 800, Riyadh 11421, Saudi Arabia
[3] KACARE Energy Res & Innovat Ctr Riyadh, Riyadh, Saudi Arabia
[4] King Saud Univ, Coll Sci, Deanship Sci Res, POB 800, Riyadh 11421, Saudi Arabia
[5] King Saud Univ, Coll Sci, Chem Dept, POB 800, Riyadh 11421, Saudi Arabia
关键词
Co-precipitation; Nanocomposite; Current-voltage; CNTs; Nano-flake; REDUCED GRAPHENE OXIDE; POSITIVE ELECTRODE; HIGH CAPACITANCE; NICKEL FOAM; CO3O4; NANOCOMPOSITE; PERFORMANCE; NANOHYBRIDS; HYDROXIDE; ARRAYS;
D O I
10.1016/j.ceramint.2021.12.350
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Fabrication of nanostructured electro-active materials with an ordered organization improved the overall performance of supercapacitor devices (SCDs). In this spirit, we developed Cu(OH)(2) nano-flakes that were statistically ordered to resemble flowers. To increase the specific capacitance and kinetics of the electroactive sample, we employed ultra-sonication to fabricate a Cu(OH)(2) nanocomposite with conductive and capacitive carbon nanotubes (CNTs). The textural and functional group analyses of the wet-chemically produced samples were completed using the XRD and FTIR techniques. I-V, FESEM, and EDX measurements Analyses of pure Cu(OH)(2) and its CNT-based nanocomposites were conducted to evaluate the materials' electrical conductivity, morphology, and chemistry, respectively. The electrochemical characteristics of the as-prepared material's electrodes were investigated, and the CNT-based nanocomposite electrode demonstrated an outstanding specific capacity (Csp) and a promising rate of performance. Our CNT-based nanocomposite had a Cs of 733 Fg(-1) at 1 Ag-1 and dropped 8.7% after 4 x 10(3) cycles. The higher electrochemical properties of the nanocomposite are governed by the nano-flakes-like architecture of the Cu (OH)(2) and the more conductive CNT matrix. According to the obtained findings, our manufactured Cu(OH)(2)/CNT based electrode has great promise for practical applications in next-generation supercapacitor, which are known to be very efficient.
引用
收藏
页码:11278 / 11285
页数:8
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