Direct fluorination of poly (p-phenylene)

被引：36
作者：
Dubois, A [1 ]
Guérin, K
Giraudet, J
Pilichowski, JF
Thomas, P
Delbé, K
Mansot, JL
Hamwi, A
机构：
[1] Univ Clermont Ferrand, UMR 6002, CNRS, Lab Mat Inorgan, F-63177 Aubiere, France
[2] Univ Clermont Ferrand, UMR 6505, CNRS, Lab Photochim Mol & Macromol, F-63177 Aubiere, France
[3] Univ Antilles Guyane, Fac Sci Exactes & Nat, CNRS, Grp Technol Surface & Interfaces,EA 2432, F-97159 Pointe a Pitre, Guadeloupe, France
来源：
POLYMER | 2005年 / 46卷 / 18期
关键词：
polymer chemistry; polymer physical chemistry;
D O I：
10.1016/j.polymer.2005.06.029
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Because of its good chemical and thermal stability due to the pi-delocalization along the polymer chain, poly(p-phenylene) was used as starting material for fluorination to obtain new carbon fluoride. A complete characterization of both the virgin polymer, in order to define parameters such as the chain length and the degree of crystallinity, and the fluorinated materials was performed by complementary techniques (F-19, H-1 and C-13 NMR, XRD, FT-IR and EPR). From these data, possible fluorination mechanisms are discussed. Finally, tribological properties have been also studied for the fluorinated samples and compared to those of conventional graphite fluorides. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：6736 / 6745
页数：10
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