Realization of atomic layer etching of silicon

An experimental system and methodology were developed to realize dry etching of single crystal silicon with monolayer accuracy. Atomic layer etching Of silicon is a cyclic process composed of four consecutive steps: reactant adsorption, excess reactant evacuation, ion irradiation, and product evacuation. When successful, completion of one cycle results in removal of one monolayer of silicon. The process was self-limiting with respect to both reactant and ion dose. Control of the ion energy was the most important factor in realizing etching of one monolayer per cycle. (C) 1996 American Vacuum Society.