Leaching Ni and Co from Saprolitic Laterite Ore by Employing Atmospheric Acid Leaching Solution with High Concentration of FeCl3 at Mild Conditions

被引:3
|
作者
Zhang, Peiyu [1 ]
Qiang, Guo [2 ]
Qu, Jingkui [2 ]
Tao, Qi [2 ]
机构
[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
laterite ore; leaching-hydrolysis coupling reactions; Ni; selective leaching; PHASE-TRANSFORMATION; REMOVAL; METALS; NICKEL; WATER;
D O I
10.3103/S1067821220010113
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Limonitic and saprolitic laterite ores are used to produce Ni by employing different kinds of processes. Acid leaching is an energy-saving process for pure Ni metal production. The high concentration of Fe in atmospheric acid leaching solution caused difficulties in metal-ions separation. In this work, saprolitic laterite ore was leached by atmospheric acid leaching solution of limonitic laterite ore at moderate temperatures. Conditions affecting the leaching of valuable metals and the conversion ratio of Fe were investigated. The results showed that optimal output was obtained after 1.5 h of leaching at 150 degrees C with 1.0 liquid/solid ratio (volume/weight). X-ray diffraction analysis and mineral liberation analysis indicate that some nickel was adsorbed by leached residues, resulting in the loss of nickel. The physiochemical properties of leached residues could be changed due to the presence of Al and Cr. The decrease in zeta potential and the increase in specific surface area resulted in the increase of Ni adsorption.
引用
收藏
页码:42 / 48
页数:7
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