A Mild and Highly Efficient Catalyst for Beckmann Rearrangement, BF3•OEt2

被引：19
作者：
An Na [1 ]
Pi Hongjun [1 ]
Liu Lifeng [1 ]
Du Wenting [1 ,2 ]
Deng Weiping [1 ]
机构：
[1] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
[2] Zhejiang Med Coll, Dept Pharm, Hangzhou 310053, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2011年 / 29卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Beckmann rearrangement; BF3 center dot OEt2; catalyst; amide; ACIDIC IONIC LIQUIDS; CYCLOHEXANONE OXIME; FACILE CONVERSION; EPSILON-CAPROLACTAM; SUPERCRITICAL WATER; BORON FLUORIDE; ACTIVE-SITES; KETOXIMES; DEHYDRATION; CHLORIDE;
D O I：
10.1002/cjoc.201190193
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
BF3 center dot OEt2 (Boron trifluoride etherate), an inexpensive and commercially easily available Lewis acid stoichiometrically employed for Beckamann rearrangement in general, was now found to efficiently catalyze Beckmann rearrangement of ketoximes into their corresponding amides (up to 99% yield) in anhydrous acetonitrile under reflux temperature.
引用
收藏
页码：947 / 950
页数：4
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