Environmentally compatible C-glycosidation of glycals using montmorillonite K-10

被引：46

作者：

Toshima, K

Miyamoto, N

Matsuo, G

Nakata, M

Matsumura, S

机构：

[1] Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama 223

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001379

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-glycosidations of glycal acetates 1-4 with allyltrimethylsilane 5, vinyloxytrimethylsilane 6 or isopropenyl acetate 7 using montmorillonite K-10 as an environmentally acceptable and inexpensive industrial catalyst under mild conditions proceed effectively to give the corresponding 2,3-unsaturated C-glycosides in high yields.

引用

页码：1379 / 1380

页数：2

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