Carbon nanotubes/TiO2 nanotubes hybrid supercapacitor

被引:42
作者
Wang, Qiang
Wen, Zhenhai
Li, Jinghong [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Anhua 230026, Peoples R China
关键词
carbon nanotubes; TiO2; nanotubes; hybrid supercapacitor;
D O I
10.1166/jnn.2007.679
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rational selection and assembly of materials are central issues in the development of energy conversion and storage applications. Incorporating the utilization of carbon nanotubes cathode and TiO2 nanotubes anode in energy storage, a nonaqueous hybrid supercapacitor was developed in order to significantly increase the energy density of the supercapacitor. The electrochemical performance of the hybrid supercapacitor is characterized by charge/discharge test and cyclic voltam-mograms. According to the voltage value, the energy density of the asymmetric supercapacitor, by applying a potential varying from 0 to 2.8 V, is found to be 14.4 Wh/kg at upwards of 10 C, which is twice more than for the conventional symmetric supercapacitor utilizing carbon nanotubes, while maintaining desirable cycling stability and rate capability.
引用
收藏
页码:3328 / 3331
页数:4
相关论文
共 22 条
[1]   An asymmetric hybrid nonaqueous energy storage cell [J].
Amatucci, GG ;
Badway, F ;
Du Pasquier, A ;
Zheng, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A930-A939
[2]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[3]   TiO2-B nanowires [J].
Armstrong, AR ;
Armstrong, G ;
Canales, J ;
Bruce, PG .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) :2286-2288
[4]   TiO2(B) nanotubes as negative electrodes for rechargeable lithium batteries [J].
Armstrong, G ;
Armstrong, AR ;
Canales, J ;
Bruce, PG .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (03) :A139-A143
[5]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[6]   Double-layer and pseudocapacitance types of electrochemical capacitors and their applications to the development of hybrid devices [J].
Conway, BE ;
Pell, WG .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2003, 7 (09) :637-644
[7]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[8]   Templated mesoporous carbons for supercapacitor application [J].
Fuertes, AB ;
Lota, G ;
Centeno, TA ;
Frackowiak, E .
ELECTROCHIMICA ACTA, 2005, 50 (14) :2799-2805
[9]   Characterization of single-wall carbon nanotubes by N2 adsorption [J].
Li, FX ;
Wang, Y ;
Wang, DZ ;
Wei, F .
CARBON, 2004, 42 (12-13) :2375-2383
[10]   Co3O4 nanomaterials in lithium-ion batteries and gas sensors [J].
Li, WY ;
Xu, LN ;
Chen, J .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (05) :851-857