Separation of an enantiomorph and its racemate by distillation: Strong chiral recognizing ability of trifluorolactates

被引：70

作者：

Katagiri, T ^{[1
]}

Yoda, C ^{[1
]}

Furuhashi, K ^{[1
]}

Ueki, K ^{[1
]}

Kubota, T ^{[1
]}

机构：

[1] IBARAKI UNIV, DEPT MAT SCI, HITACHI, IBARAKI 316, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 02期

关键词：

D O I：

10.1246/cl.1996.115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifluorolactate experienced modification of its enantiomeric excess by fractional distillation. Quantitative studies have shown that the separation of an enantiomorph and its racemate is due to a change in boiling points that depend on the enantiomeric excess of the compound. Such a change in the boiling point was not seen in the case of the non fluorinated lactate.

引用

页码：115 / 116

页数：2

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