[N-(2-Aminoethyl)-N-(2-{(E)-[9-(diethoxymethyl)-1,10-phenanthrolin-2-yl]-methylideneamino}ethyl)ethane-1,2-diamine]copper(II) bis(perchlorate)

被引：1
|
作者：
Keypour, Hassan [1 ]
Goudarziafshar, Hamid
Brisdon, Alan K.
Pritchard, Robin G.
机构：
[1] Bu Ali Sina Univ, Fac Chem, Hamadan 65174, Iran
[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807032953
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [CU(C24H34N6O2)]CIO4)(2), the copper(II) coordination geometry is intermediate between square-based-pyramidal and trigonal-bipyramidal. The H atoms of the sixth non-metal-coordinating nitrogen donor engage in intramolecular hydrogen bonding with the ethoxy O atom and the uncoordinated phenanthroline N atom. Hydrogen bonding is also observed between the NH2 H atoms and two of the phenanthroline H atoms with the perchlorate anions.
引用
收藏
页码：M2158 / U1194
页数：15
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