Recent Applications of Polymer Supported Organometallic Catalysts in Organic Synthesis

被引：70

作者：

Kann, Nina ^{[1
]}

机构：

[1] Chalmers Univ Technol, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden

来源：

MOLECULES | 2010年 / 15卷 / 09期

基金：

瑞典研究理事会;

关键词：

polymer supported; organometallic; solid phase synthesis; cross-coupling; metathesis; allylic substitution; transfer hydrogenation; aryl amination; ACROLEIN DIETHYL ACETAL; N-HETEROCYCLIC CARBENES; SOLID-PHASE SYNTHESIS; MIZOROKI-HECK; C-C; ASYMMETRIC CYCLOPROPANATION; INCARCERATED PALLADIUM; RECYCLABLE CATALYST; COUPLING REACTIONS; HIGHLY EFFICIENT;

D O I：

10.3390/molecules15096306

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but also aryl amination, epoxide opening, rearrangements, metathesis and cyclopropanation. Applications in the field of asymmetric synthesis are also discussed.

引用

页码：6306 / 6331

页数：26

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