3-(4-Fluorophenylsulfinyl)-5-iodo-2methyl-1-benzofuran

被引:2
作者
Choi, Hong Dae [2 ]
Seo, Pil Ja [2 ]
Son, Byeng Wha [1 ]
Lee, Uk [1 ]
机构
[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea
[2] Dong Eui Univ, Dept Chem, Pusan 614714, South Korea
关键词
BENZOFURAN;
D O I
10.1107/S1600536810024931
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H10FIO2S, the O atom and the 4-fluorophenyl group of the 4-fluorophenylsulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment; the 4-fluorophenyl ring is nearly perpendicular to this plane, making a dihedral angle of 83.37 (7)degrees. The crystal structure is stabilized by weak intermolecular C-H center dot center dot center dot O hydrogen bonds and an I center dot center dot center dot O interaction [I center dot center dot center dot O = 3.255 (2) angstrom]. The crystal structure also exhibits intermolecular C-F center dot center dot center dot pi interactions [3.068 (2) angstrom], and aromatic pi-pi interactions between the furan and benzene rings of neighbouring benzofuran fragments [centroid-centroid distance = 3.636 (2) angstrom].
引用
收藏
页码:O1876 / U1188
页数:10
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