Ruthenium(II) complexes derived from 2-phenylthiazoline-4-carboxylic acid: structure and catalytic activity for transfer hydrogenation reaction

被引：8
作者：
Denizalti, Serpil [1 ]
Sen, Betul [2 ]
Gokce, Aytac Gurhan [2 ]
Cetinkaya, Bekir [1 ]
机构：
[1] Ege Univ, Dept Chem, TR-35100 Bornova, Turkey
[2] Dokuz Eylul Univ, Dept Phys, TR-35160 Buca Izmir, Turkey
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2016年 / 30卷 / 05期
关键词：
ruthenium complex; thiazoline; transfer hydrogenation; ASYMMETRIC TRANSFER HYDROGENATION; CARBOXYLATE LIGANDS; NITROSYL COMPLEXES; COORDINATION MODE; DIPICOLINIC ACID; REDOX PROPERTIES; AMINO-ACID; KETONES; SUBSTITUTION; ANALOGS;
D O I：
10.1002/aoc.3442
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Piano-stool ([(p-cymene)Ru(thz)Cl], 2) and six-coordinated ([Ru(thz)(2)(PPh3)(2)], 3) ruthenium complexes derived from 2-phenylthiazoline-4-carboxylic acid (Hthz, 1) were synthesized for the first time, and fully characterized using conventional methods. Also, the molecular structure of complex 3 was determined using X-ray analysis. These complexes were evaluated as catalysts for transfer hydrogenation of carbonyl compounds in the presence of isopropyl alcohol and (KOBu)-Bu-t. Complex 2 was found to be more active than 3 in transfer hydrogenation. Copyright (c) 2016 John Wiley & Sons, Ltd.
引用
收藏
页码：373 / 377
页数：5
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