FACILE MICROWAVE -ASSISTED SYNTHESIS OF CASEIN DERIVED CARBON NANODOTS

被引:1
作者
Pricilla, R. Blessy [1 ]
Skoda, David [1 ]
Urbanek, Pavel [1 ]
Urbanek, Michal [1 ]
Kuritka, Ivo [1 ]
机构
[1] Tomas Bata Univ Zlin, Ctr Polymer Syst, Zlin, Czech Republic
来源
12TH INTERNATIONAL CONFERENCE ON NANOMATERIALS - RESEARCH & APPLICATION (NANOCON 2020) | 2021年
关键词
Carbon nanodots; casein; microwave reactor; Polyvinylpyrrolidone; DOTS; EMISSION; LIGHT; PHOTOLUMINESCENCE; PROTEIN; GREEN; MILK; RED;
D O I
10.37904/nanocon.2020.3681
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Belonging to the carbon family, yet standing apart, carbon nanodots are materials with excellent properties. Among them, they are well known for their attractive optical properties. The insight into this outstanding strength has resulted in the discovery of unique design of materials. These nanodots can be prepared via various methods to obtain a good optical response. In our research, we synthesized them using a microwave reactor, which is simple, fast and productive. As a carbon source casein, a low-cost precursor was used. Since this is a protein composed of amino acids, no additional passivation was required. Polyvinylpyrrolidone was used as a stabilizer for the nanodots. The synthesis was carried out at 200 degrees C for 30 minutes. The color change of the resulting solution to orange brown indicates the formation of carbon nanodots. These nanodots were filtered and dialyzed to be used for further characterizations. The carbon nanodots were spherical with the average size of about 9.7 nm. They showed a strong blue emission in the visible region with an appreciable quantum yield. One of the important characteristics of this method is the availability of reasonably good product yield. The prepared carbon nanodots have potential applications in the field of electrochemistry, optoelectronics and biological imaging.
引用
收藏
页码:75 / 79
页数:5
相关论文
共 20 条
[1]   Blue light-emitting carbon dots (CDs) from a milk protein and their interaction with Spinacia oleracea leaf cells [J].
Bajpai, S. K. ;
D'Souza, A. ;
Suhail, Basharat .
INTERNATIONAL NANO LETTERS, 2019, 9 (03) :203-212
[2]   Semiconductor and carbon-based fluorescent nanodots: the need for consistency [J].
Cayuela, A. ;
Soriano, M. L. ;
Carrillo-Carrion, C. ;
Valcarcel, M. .
CHEMICAL COMMUNICATIONS, 2016, 52 (07) :1311-1326
[3]   Microwave-assisted synthesis of carbon dots and their applications [J].
de Medeiros, Tayline V. ;
Manioudakis, John ;
Noun, Farah ;
Macairan, Jun-Ray ;
Victoria, Florence ;
Naccache, Rafik .
JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (24) :7175-7195
[4]   Full-Color Light-Emitting Carbon Dots with a Surface-State-Controlled Luminescence Mechanism [J].
Ding, Hui ;
Yu, Shang-Bo ;
Wei, Ji-Shi ;
Xiong, Huan-Ming .
ACS NANO, 2016, 10 (01) :484-491
[5]   Photoluminescence of Carbon Nanodots: Dipole Emission Centers and Electron-Phonon Coupling [J].
Ghosh, Siddharth ;
Chizhik, Anna M. ;
Karedla, Narain ;
Dekaliuk, Manila O. ;
Gregor, Ingo ;
Schuhmann, Henning ;
Seibt, Michael ;
Bodensiek, Kai ;
Schaap, Iwan A. T. ;
Schulz, Olaf ;
Demchenko, Alexander P. ;
Enderlein, Joerg ;
Chizhik, Alexey I. .
NANO LETTERS, 2014, 14 (10) :5656-5661
[6]   Red, Green, and Blue Luminescence by Carbon Dots: Full-Color Emission Tuning and Multicolor Cellular Imaging [J].
Jiang, Kai ;
Sun, Shan ;
Zhang, Ling ;
Lu, Yue ;
Wu, Aiguo ;
Cai, Congzhong ;
Lin, Hengwei .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (18) :5360-5363
[7]   A hydrothermal reaction of an aqueous solution of BSA yields highly fluorescent N doped C-dots used for imaging of live mammalian cells [J].
Kumar, Vijay Bhooshan ;
Sheinberger, Jonathan ;
Porat, Zeev ;
Shav-Tal, Yaron ;
Gedanken, Aharon .
JOURNAL OF MATERIALS CHEMISTRY B, 2016, 4 (17) :2913-2920
[8]   Direct white light emission from carbon nanodots ( C- dots) in solution processed light emitting diodes [J].
Paulo-Mirasol, Sofia ;
Martinez-Ferrero, Eugenia ;
Palomares, Emilio .
NANOSCALE, 2019, 11 (23) :11315-11321
[9]   Laser Ablated Carbon Nanodots for Light Emission [J].
Reyes, Delfino ;
Camacho, Marco ;
Camacho, Miguel ;
Mayorga, Miguel ;
Weathers, Duncan ;
Salamo, Greg ;
Wang, Zhiming ;
Neogi, Arup .
NANOSCALE RESEARCH LETTERS, 2016, 11
[10]   Protein-derived carbon nanodots with an ethylenediamine-modulated structure as sensitive fluorescent probes for Cu2+ detection [J].
Sai, Liman ;
Chen, Jun ;
Chang, Quanhong ;
Shi, Wangzhou ;
Chen, Qi ;
Huang, Lei .
RSC ADVANCES, 2017, 7 (27) :16608-16615