Total synthesis of natural products via iridium catalysis

被引：39
作者：
Yuan, Changchun [1 ]
Liu, Bo [2 ]
机构：
[1] North Univ China, Sch Chem Engn & Technol, Taiyuan 030051, Shanxi, Peoples R China
[2] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 01期
关键词：
ENANTIOSELECTIVE TOTAL-SYNTHESIS; C-H BORYLATION; FORMAL TOTAL-SYNTHESIS; ABSOLUTE STEREOCHEMICAL ASSIGNMENT; ALLYLIC DEAROMATIZATION REACTION; CARBON QUATERNARY STEREOCENTERS; NITROGEN BRIDGEHEAD COMPOUNDS; LIGHT PHOTOREDOX CATALYSIS; ASYMMETRIC TOTAL-SYNTHESIS; DIVERGENT TOTAL-SYNTHESIS;
D O I：
10.1039/c7qo00664k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalysis with transition metals is a powerful synthetic tool for achieving a high degree of molecular complexity from relatively simple building blocks. Among these transition metals employed, iridium has attracted significant attention owing to its multifold roles in catalysis of various synthetically significant methodologies, and thus iridium catalysts are widely used in natural product synthesis. This review aims to comprehensively summarize recent accomplishments in total synthesis of natural products using iridium as the catalyst.
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收藏
页码：106 / 131
页数：26
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