High fidelity sorting of remarkably similar components via metal-mediated assembly

被引：24

作者：

Holloway, Lauren R. ^{[1
]}

Young, Michael C. ^{[1
]}

Beran, Gregory J. O. ^{[1
]}

Hooley, Richard J. ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

CHEMICAL SCIENCE | 2015年 / 6卷 / 08期

基金：

美国国家科学基金会;

关键词：

SUPRAMOLECULAR SYSTEMS; CAGE; COMPLEXES; FUNCTIONALITY; ENCAPSULATION; CONSTRUCTION; RECOGNITION; CHEMISTRY; POLYGONS; DESIGN;

D O I：

10.1039/c5sc01689d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Subtle differences in ligand coordination angle and rigidity lead to high fidelity sorting between individual components displaying identical coordination motifs upon metal-mediated self-assembly. Narcissistic self-sorting can be achieved between highly similar ligands that vary minimally in rigidity and internal coordination angle upon combination with Fe(II) ions and 2-formylpyridine. Selective, sequential cage formation can be precisely controlled in a single flask from a mix of three different core ligands (and 33 total components) differing only in the hybridization of one group that is uninvolved in the metal coordination process.

引用

页码：4801 / 4806

页数：6

共 42 条

[1] Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation [J].

Acharyya, Koushik ;

Mukherjee, Sandip ;

Mukherjee, Partha Sarathi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) :554-557

[2] Disproportionation and self-sorting in molecular encapsulation [J].

Ajami, Dariush ;

Hou, Jun-Li ;

Dale, Trevor J. ;

Barrett, Elizabeth ;

Rebek, Julius, Jr. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (26) :10430-10434

[3] The Self-Sorting Behavior of Circular Helicates and Molecular Knots and Links [J].

Ayme, Jean-Francois ;

Beves, Jonathon E. ;

Campbell, Christopher J. ;

Leigh, David A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (30) :7823-7827

[4] Subcomponent Self-Assembly and Guest-Binding Properties of Face-Capped Fe4L48+ Capsules [J].

Bilbeisi, Rana A. ;

Clegg, Jack K. ;

Elgrishi, Noemie ;

de Hatten, Xavier ;

Devillard, Marc ;

Breiner, Boris ;

Mal, Prasenjit ;

Nitschke, Jonathan R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (11) :5110-5119

[5] Effects of subtle differences in ligand constitution and conformation in metallo-supramolecular self-assembled polygons [J].

Brusilowskij, Boris ;

Dzyuba, Egor V. ;

Troff, Ralf W. ;

Schalley, Christoph A. .

DALTON TRANSACTIONS, 2011, 40 (45) :12089-12096

[6] Reassembly self-sorting triggered by heterodimerization [J].

Cao, Li-Ping ;

Wang, Jun-Gang ;

Ding, Jiao-Yang ;

Wu, An-Xin ;

Isaacs, Lyle .

CHEMICAL COMMUNICATIONS, 2011, 47 (30) :8548-8550

[7] Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].

Cook, Timothy R. ;

Zheng, Yao-Rong ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2013, 113 (01) :734-777

[8] Giant hollow MnL2n spherical complexes: structure, functionalisation and applications [J].

Harris, Kate ;

Fujita, Daishi ;

Fujita, Makoto .

CHEMICAL COMMUNICATIONS, 2013, 49 (60) :6703-6712

[9] A weak attractive interaction between organic fluorine and an amide group [J].

Hof, F ;

Scofield, DM ;

Schweizer, WB ;

Diederich, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :5056-5059

[10] Selective Encapsulation and Sequential Release of Guests Within a Self-Sorting Mixture of Three Tetrahedral Cages [J].

Jimenez, Azucena ;

Bilbeisi, Rana A. ;

Ronson, Tanya K. ;

Zarra, Salvatore ;

Woodhead, Craig ;

Nitschke, Jonathan R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (18) :4556-4560

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