A three-dimensional ferrimagnet composed of mixed-valence Mn4 clusters linked by an {Mn[N(CN)2]6}4- unit

被引：149
|
作者：
Miyasaka, H
Nakata, K
Sugiura, K
Yamashita, M
Clérac, R
机构：
[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan
[2] Japanese Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
[3] CNRS, Ctr Rech Paul Pascal, UPR 8641, F-33600 Pessac, France
[4] Japanese Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 06期
关键词：
D O I：
10.1002/anie.200353093
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ferrimagnet with a 3D molecular network (depicted) has been synthesized and characterized. The compound is composed of units of mixed-valence Mn 4 clusters, a unit that is well known for its single-molecule magnet properties, and MnII paramagnetic units. Both building blocks are linked by a dicyanamide bridging ligand to form a covalently bonded three-dimensional network. The compound becomes a ferrimagnet at 4.1 K that exhibits a spin-flip phenomenon under the influence of a magnetic field.
引用
收藏
页码：707 / 711
页数：5
相关论文
共 50 条
  • [1] [Mn(en)]3[Cr(CN)6]2• 4H2O:: A three-dimensional dimetallic ferrimagnet (Tc=69 K) with a defective cubane unit
    Ohba, M
    Usuki, N
    Fukita, N
    Okawa, H
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (12) : 1795 - 1798
  • [2] New Mixed-Valent Mn Clusters from the Use of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine (edteH4): Mn3, Mn4 Mn6, and Mn10
    Saha, Arpita
    Abboud, Khalil A.
    Christou, George
    INORGANIC CHEMISTRY, 2011, 50 (24) : 12774 - 12784
  • [3] High-spin Mn4 and Mn10 molecules:: Large spin changes with structure in mixed-valence MnII4MnIII6 clusters with azide and alkoxide-based ligands
    Stamatatos, Theocharis C.
    Poole, Katye M.
    Abboud, Khalil A.
    Wernsdorfer, Wolfgang
    O'Brien, Ted A.
    Christou, George
    INORGANIC CHEMISTRY, 2008, 47 (11) : 5006 - 5021
  • [4] [Mn(C4H10ON)(H2O)][Fe(CN)6]: A Three-Dimensional Cyanide-Bridged Ferrimagnet with a Morpholine Ligand
    Jiang, Ning
    Li, Feng-Yan
    Xu, Lin
    Zhao, Li-Li
    Wang, Yu-Chao
    INORGANIC CHEMISTRY, 2011, 50 (04) : 1544 - 1550
  • [5] MN2+/MN3+ AND MN3+/MN4+ MIXED-VALENCE BINUCLEAR MANGANESE COMPLEXES OF BIOLOGICAL INTEREST
    DISMUKES, GC
    SHEATS, JE
    SMEGAL, JA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) : 7202 - 7203
  • [6] Mn4, Mn6, and Mn11 Clusters from the Use of Bulky Diphenyl(pyridine-2-yl)methanol
    Taguchi, Taketo
    Daniels, Matthew R.
    Abboud, Khalil A.
    Christou, George
    INORGANIC CHEMISTRY, 2009, 48 (19) : 9325 - 9335
  • [7] A Family of 3-D Coordination Polymers Composed of Mixed-Valence Mn6 Octahedra within Na4 Tetrahedra
    Stamatatos, Theocharis C.
    Abboud, Khalil A.
    Christou, George
    JOURNAL OF CLUSTER SCIENCE, 2010, 21 (03) : 485 - 501
  • [8] A Family of 3-D Coordination Polymers Composed of Mixed-Valence Mn6 Octahedra within Na4 Tetrahedra
    Theocharis C. Stamatatos
    Khalil A. Abboud
    George Christou
    Journal of Cluster Science, 2010, 21 : 485 - 501
  • [9] Distribution of mixed-valence ions in Mn1+xFe2-xO4 ferrites
    Aoyagi, Y.
    Okube, M.
    Sasaki, S.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2014, 70 : C1354 - C1354
  • [10] Aggregation of Hexanuclear, Mixed-Valence Manganese Oxide Clusters Linked by Propionato Ligands To Form a One-Dimensional Polymer [Mn6O2(O2CEt)10(H2O)4]n
    Ma, Cheng-Bing
    Hu, Ming-Qiang
    Chen, Hui
    Chen, Chang-Neng
    Liu, Qiu-Tian
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (33) : 5274 - 5280
12345