Controlled Positioning of Activated Ester Moieties on Well-Defined Linear Polymer Chains

被引：43
|
作者：
Kakuchi, Ryohei [2 ]
Zamfir, Mirela [1 ]
Lutz, Jean-Francois [1 ]
Theato, Patrick [2 ]
机构：
[1] CNRS, Inst Charles Sadron, Precis Macromol Chem Grp, UPR22, F-67034 Strasbourg 2, France
[2] Univ Hamburg, Inst Tech & Macromol Chem, D-20146 Hamburg, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2012年 / 33卷 / 01期
基金：
欧洲研究理事会;
关键词：
functional polymers primary structure; functional polymers; post-polymerization modification; nitroxide mediated polymerization (NMP); SELECTIVE RADICAL-ADDITION; PRECISION POLYMERS; SEQUENCE; MONOMER; CHEMISTRY;
D O I：
10.1002/marc.201100611
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The successful sequence-controlled installation of an activated ester using a newly designed monomer pentafluorophenyl 4-maleimidobenzoate is demonstrated. Pentafluorophenyl 4-maleimidobenzoate is kinetically installed at different stages of a nitroxide-mediated polymerization, namely, near the a-chain end and in the middle of a PS chain. In addition, successful installation of apolar and polar functional groups is achieved via post-polymerization functionalization, which demonstrated the versatility of the synthesis of a universal precursor for locally functionalized polymers.
引用
收藏
页码：54 / 60
页数：7
相关论文
共 50 条
  • [31] Need for well-defined macromolecules on the frontiers of polymer science and technology
    Lohse, David J.
    Hadjichristidis, Nikos
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
  • [32] Biomolecular building blocks for well-defined polymer architectures.
    van Hest, JCM
    Spijker, H
    Ayres, L
    Opsteen, J
    Smeenk, J
    Adams, H
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U644 - U644
  • [33] INVESTIGATION OF THE POLYMER INTERPHASE VIA SYNTHESIS OF WELL-DEFINED COPOLYMERS
    SMITH, SD
    SATKOWSKI, MM
    NODA, I
    MARCOTT, C
    DOWREY, AE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 33 - COLL
  • [34] Synthesis and electrospinning of well-defined polymer brushes by modification of polyacrylonitrile
    Beifang Liu
    Ye Liu
    Yuxue Wang
    Hong Man
    Wenxiang Wang
    Hou Chen
    Liangjiu Bai
    Journal of Polymer Research, 2018, 25
  • [35] Well-defined protein–polymer conjugates—synthesis and potential applications
    Pall Thordarson
    Benjamin Le Droumaguet
    Kelly Velonia
    Applied Microbiology and Biotechnology, 2006, 73 : 243 - 254
  • [36] Design of a Well-Defined Polyrotaxane Structure on a Glassy Polymer Surface
    Taneda, Hidenobu
    Shundo, Atsuomi
    Matsuno, Hisao
    Tanaka, Keiji
    LANGMUIR, 2018, 34 (02) : 709 - 714
  • [37] Synthesis of well-defined protein-polymer conjugates for biomedicine
    Zhao, Wenguo
    Liu, Fei
    Chen, Yue
    Bai, Jing
    Gao, Weiping
    POLYMER, 2015, 66 : A1 - A10
  • [38] Synthesis and electrospinning of well-defined polymer brushes by modification of polyacrylonitrile
    Liu, Beifang
    Liu, Ye
    Wang, Yuxue
    Man, Hong
    Wang, Wenxiang
    Chen, Hou
    Bai, Liangjiu
    JOURNAL OF POLYMER RESEARCH, 2017, 25 (01)
  • [39] Well-defined linear multiblock and branched polypeptides by linking chemistry
    Aliferis, T
    Iatrou, H
    Hadjichristidis, N
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (19) : 4670 - 4673
  • [40] Synthesis of well-defined polymer architectures by successive catalytic olefin polymerization and living/controlled polymerization reactions
    Godoy Lopez, Ricardo
    D'Agosto, Franck
    Boisson, Christophe
    PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) : 419 - 454
12345