Controlled Positioning of Activated Ester Moieties on Well-Defined Linear Polymer Chains

被引：43
|
作者：
Kakuchi, Ryohei [2 ]
Zamfir, Mirela [1 ]
Lutz, Jean-Francois [1 ]
Theato, Patrick [2 ]
机构：
[1] CNRS, Inst Charles Sadron, Precis Macromol Chem Grp, UPR22, F-67034 Strasbourg 2, France
[2] Univ Hamburg, Inst Tech & Macromol Chem, D-20146 Hamburg, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2012年 / 33卷 / 01期
基金：
欧洲研究理事会;
关键词：
functional polymers primary structure; functional polymers; post-polymerization modification; nitroxide mediated polymerization (NMP); SELECTIVE RADICAL-ADDITION; PRECISION POLYMERS; SEQUENCE; MONOMER; CHEMISTRY;
D O I：
10.1002/marc.201100611
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The successful sequence-controlled installation of an activated ester using a newly designed monomer pentafluorophenyl 4-maleimidobenzoate is demonstrated. Pentafluorophenyl 4-maleimidobenzoate is kinetically installed at different stages of a nitroxide-mediated polymerization, namely, near the a-chain end and in the middle of a PS chain. In addition, successful installation of apolar and polar functional groups is achieved via post-polymerization functionalization, which demonstrated the versatility of the synthesis of a universal precursor for locally functionalized polymers.
引用
收藏
页码：54 / 60
页数：7
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